- 1940 Roberta Kelly Shiner Randolph Slaughter
- 1941 Hazel Kepley Powell John Ward
- 1942 Corinne Hamilton Slaughter Alvin Hansen
- 1943 Amy Purnell W. T. Neblett
- 1944 Ophelia Thurmond Slaughter James Moore, Jr.
- 1945 Myrlee Wright McNary Joseph C. May
- 1946 Sue Brennan O’Hern William N. Hall
- 1947 Odette Bunn Moore Carlos Richter
- 1948 Lula Bryant Lacey Paul Sulak
- 1949 Daisy Brewer Gilliland George Penny
- 1950 Lois Foster Sullivan Sam Sullivan
- 1951 Angela Scovazzo Borchers Elmore H. Borchers, Sr.
- 1952 Frances Walla Sulak Vern Kegler
- 1953 Anita Ligarde Martin A. E. Guajardo
- 1954 Diana Maria Lafon John Hurd
- 1955 Roslyn Alexander Mandel Francis Richter
- 1956 Mary Louise Mumm Longoria George Longoria
- 1957 Elvella Dinn Mann Ed Mann
- 1958 Lilia Longoria Bruni Thomas A. Leyendecker, Jr.
- 1959 Claire Derby Yates Thomas Hugh Yates
- 1960 Isla Lewis Herring Lawrence Wright
- 1961 Lola de Llano Jackson George O. Jackson
- 1962 Marguerite Martin Volz Arthur Volz
- 1963 Helen Kahn Pellegrin Carlton Whitworth
- 1964 Maria Luisa Rangel Kahn Honore Ligarde
- 1965 Olga Rosenbaum Meyer Robert Trautmann
- 1966 Bruna Puig Sutton J. W. Nixon
- 1967 Minnie Dora Martin Bunn Gaillard R. Peck
- 1968 Susy Neel Mayo Samuel Meyer
- 1969 Elizabeth Kowalski Foster Joseph C. Martin, Jr.
- 1970 Wanda Bessan Garner Valentin L. Puig, Jr.
- 1971 Patricia Brand Sanditen Fernando F. Zuniga, Jr.
- 1972 Barbara Tucker Powell William R. Powell, Jr.
- 1973 Sheila Slaughter Glassford Max Mandel
- 1974 Lamar Kahn Gallagher Edward R. Leyendecker
- 1975 Josephine Palacios Zuniga George Edward Glassford
- 1976 Ella Douglas Howland Thomas High Yates, Jr.
- 1977 Julie Schaifer Watson Horace Watson, Jr.
- 1978 Mary Boone Lowry Ervin Kyle A. Ervin, Jr.
- 1979 Julia Watson Jones Samuel N. Johnson, Jr.
- 1980 Anita Palacios Macdonald Abe Wilson
- 1981 Consuela Sada Canseco Joseph G. Schneidler
- 1982 Millicent Brown Slaughter George E. Macdonald
- 1983 Rosalie Kowalski Goodman George P. Kazen
- 1984 Nora E. Gonzalez Montemayor Alan Jackson
- 1985 Julieta Farias Staggs Franck M. Staggs
- 1986 Mary Alyce Corrigan Douglas G. Macdonald
- 1987 Ana Perez Garcia Zuniga Carroll E. Summers, Jr.
- 1988 Evelyn Bruni Summers Peter R. Arguindegui, Jr.
- 1989 Barbara Sanders Kazen William Nesbitt Hall, Jr.
- 1990 Ellen Bailey Young Marcel Notzon
- 1991 Carole Weber Wilson Harry Elias Sames, III
- 1992 Linda Brand Deutsch Fernando F. Zuniga, III
- 1993 Nora Lee Haynes Notzon Jerome Jordan
- 1994 Violeta Garza Zertuche Marvin Melson
- 1995 Linda Jacaman Bruni Ernest Martin Bruni, Jr.
- 1996 Jeanette Moser G. Edward Macdonald, Jr.
- 1997 Mary Leyendecker Quiros Evan James Quiros
- 1998 Deborah Snyder Portman David March Slaughter, Jr.
- 1999 Altagracia Azios Garcia Hector H. Garcia
- 2000 Mary Susan Foster Francisco Raul Canseco
- 2001 Annabelle Uribe Hall John mayo McKeown
- 2002 Janice Gallagher Gonzalez Paul Herman Young, Jr.
- 2003 Rosanne Winch Potts Aladar Deutsch, Jr.
- 2004 Lorraine Withoff Laurel Federico C. Zuniga
- 2005 Anita Zuniga Dodier Richard E. Haynes
- 2006 Mary Reynolds Kazen Robert Hill Summers
- 2007 Adrienne Goodman Trevino James Aloysuis Notzon
- 2008 Mary Lamar Leyendecker Thomas Albert Gates
- 2009 Veronica Casillas Castillon Ray M. Keck, III
- 2010 Anna Benavides Galo John Clifford Galo
- 2011 Betty Ann Bunn Moreno Francis Cullen Averill, Jr.
- 2012 Anita Fansler Averill Oscar Moreno
- 2013 Ana Lamar Gutierrez Volpe Tad Lawrence Deutsch
- 2014 Rebecca Mata Laurel Henry Cuellar
- 2015 Melissa Cantu Cigarroa Gabriel Cesar Castillo
- 2016 Minnie Dora Bunn Haynes Richard Edward Mims
- 2017 Linda Lopez Howland Douglas Blair Howland
- 2018 Tami Dorsett Summers Timothy Guy Shipton
- 2019 Anna Isabel Garcia Alvarez Ernest Martin Bruni, III
- 2020 Elizabeth Jones Rubio Jose M. Rubio, Jr.
- 2021 Irma De La Miyar Deutsch Joe Castellano
- 2022 Kristina Laurel Hale Oscar J. Hale, Jr.
- 2023 Linda Cristina Benavides Jose Antonio Palacios, Jr.
- 2024 Alison White Haynes Richard E. Haynes, II
- 2025 Minnie Dora Haynes Rodriguez Russell Lee Cerda
- 2026 Nydia Sanchez Weathers James Robert Weathers